
Aluminium Chloride Anhydrous AR -100g
Aluminium Chloride Anhydrous AR is a white to yellowish solid, widely used as a Lewis acid catalyst in organic synthesis, particularly in Friedel–Crafts reactions, and in analytical chemistry applications.
Chemical Name:
Aluminium Chloride (anhydrous)
Chemical Formula:
AlCl₃
Grade & Quantity:
AR Grade (Analytical Reagent) – commonly available in 100g, 250g, or 500g
CAS Number:
7446-70-0
Appearance:
White to pale yellow crystalline powder; fumes in moist air due to hydrolysis
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A weak organic acid in crystalline powder form, commonly used as an acidulant, preservative, and cleaning agent.
Synonyms:
2-Hydroxy-1,2,3-propane-tricarboxylic acid, anhydrous citric acid
CAS Number:
77-92-9
Appearance:
White crystalline powder, odorless, soluble in water
Common Uses:
-
Catalyst in Friedel–Crafts alkylation and acylation reactions
-
Used in dye intermediates, pharmaceuticals, and fragrances
-
Reagent in analytical chemistry and inorganic synthesis
Key Features:
-
Powerful Lewis acid with high reactivity
-
Highly hygroscopic – reacts with moisture to form HCl
-
Ideal for anhydrous, controlled environment applications
-
Suitable for laboratory and industrial catalysis
SDS (Safety Summary):
-
Corrosive – causes severe burns to skin, eyes, and respiratory tract
-
Reacts violently with water and moist air
-
Use gloves, goggles, lab coat, and fume hood
-
Store in airtight container, away from moisture and bases
- Product Name: Aluminium Chloride Anhydrous AR
- Synonyms: Anhydrous Aluminum Chloride
- CAS Number: 7446-70-0
- Intended Use: Analytical reagent, laboratory chemical
Section 2: Hazard(s) Identification
- Hazard Classification:
- Corrosive to metals (Category 1)
- Acute toxicity, Oral (Category 4)
- Skin corrosion/irritation (Category 1B)
- Serious eye damage/eye irritation (Category 1)
- Signal Word: Danger
- Hazard Statements:
- H290: May be corrosive to metals
- H302: Harmful if swallowed
- H314: Causes severe skin burns and eye damage
- Precautionary Statements:
- P234: Keep only in original container
- P264: Wash hands thoroughly after handling
- P270: Do not eat, drink, or smoke when using this product
- P280: Wear protective gloves/protective clothing/eye protection/face protection
- P301+P330+P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
- P303+P361+P353: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower
- P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
- P310: Immediately call a POISON CENTER/doctor
- P390: Absorb spillage to prevent material damage
- P501: Dispose of contents/container in accordance with local/regional/national/international regulations
Section 3: Composition/Information on Ingredients
- Chemical Name: Aluminium Chloride Anhydrous
- CAS Number: 7446-70-0
- EINECS Number: 231-208-1
- Molecular Formula: AlCl₃
- Molecular Weight: 133.34 g/mol
Section 4: First-Aid Measures
- Inhalation: Move to fresh air. If symptoms persist, seek medical attention.
- Skin Contact: Wash off immediately with soap and plenty of water. Remove contaminated clothing. Seek immediate medical attention.
- Eye Contact: Rinse immediately with plenty of water for at least 15 minutes. Seek immediate medical attention.
- Ingestion: Rinse mouth with water. Do not induce vomiting. Seek immediate medical attention.
Section 5: Fire-Fighting Measures
- Suitable Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide.
- Specific Hazards: Hydrogen chloride gas, aluminum oxides.
- Protective Equipment: Firefighters should wear self-contained breathing apparatus (SCBA) and full protective clothing.
Section 6: Accidental Release Measures
- Personal Precautions: Use personal protective equipment. Avoid breathing dust, vapors, mist, or gas. Ensure adequate ventilation. Evacuate personnel to safe areas.
- Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
- Clean-up Methods: Sweep up and shovel. Keep in suitable, closed containers for disposal. Avoid generating dust.
Section 7: Handling and Storage
- Handling: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed. Do not breathe dust or mist.
- Storage: Store in a cool, dry, well-ventilated place. Keep container tightly closed. Keep away from water, moisture, and incompatible materials.
Section 8: Exposure Controls/Personal Protection
- Engineering Controls: Ensure adequate ventilation, especially in confined areas. Use corrosion-resistant ventilation systems.
- Personal Protective Equipment (PPE):
- Respiratory Protection: Use NIOSH-approved respirators if ventilation is inadequate.
- Hand Protection: Chemical-resistant gloves.
- Eye Protection: Safety goggles or face shield.
- Skin and Body Protection: Lab coat or chemical-resistant apron.
Section 9: Physical and Chemical Properties
- Appearance: White to pale yellow crystalline powder
- Odor: Pungent, characteristic odor
- Odor Threshold: Not available
- pH: Not available
- Melting Point/Freezing Point: 190°C (374°F)
- Boiling Point/Range: Sublimes at 178°C (352°F)
- Flash Point: Not applicable
- Evaporation Rate: Not applicable
- Flammability: Non-flammable
- Upper/Lower Flammability or Explosive Limits: Not applicable
- Vapor Pressure: Not available
- Vapor Density: Not available
- Relative Density: 2.44 g/cm³
- Solubility: Reacts with water
- Partition Coefficient (n-octanol/water): Not available
- Auto-ignition Temperature: Not available
- Decomposition Temperature: Not available
- Viscosity: Not applicable
Section 10: Stability and Reactivity
- Reactivity: Reacts violently with water.
- Chemical Stability: Stable under recommended storage conditions.
- Possibility of Hazardous Reactions: Reacts violently with water, forming hydrochloric acid.
- Conditions to Avoid: Avoid moisture, water, and humid air.
- Incompatible Materials: Water, bases, and strong oxidizing agents.
- Hazardous Decomposition Products: Hydrogen chloride gas, aluminum oxides.
Section 11: Toxicological Information
- Acute Toxicity: LD50 Oral – rat – 3,450 mg/kg
- Skin Corrosion/Irritation: Causes severe skin burns.
- Serious Eye Damage/Irritation: Causes severe eye damage.
- Respiratory or Skin Sensitization: Not classified.
- Germ Cell Mutagenicity: Not classified.
- Carcinogenicity: Not classified by IARC, NTP, OSHA.
- Reproductive Toxicity: Not classified.
- Specific Target Organ Toxicity – Single Exposure: Not classified.
- Specific Target Organ Toxicity – Repeated Exposure: Not classified.
- Aspiration Hazard: Not classified.
| Weight | 1 kg |
|---|
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