
Toluene – 25Lt
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A weak organic acid in crystalline powder form, commonly used as an acidulant, preservative, and cleaning agent.
Synonyms:
2-Hydroxy-1,2,3-propane-tricarboxylic acid, anhydrous citric acid
CAS Number:
77-92-9
Appearance:
White crystalline powder, odorless, soluble in water
Section 1: Identification
Product Name: Toluene
Synonyms: Methylbenzene, Phenylmethane
CAS Number: 108-88-3
Chemical Formula: C₆H₅CH₃
Recommended Uses: Toluene is commonly used as a solvent in various industrial applications, including paint thinners, adhesives, and coatings.
Section 2: Hazard Identification
Classification:
- Acute Toxicity (Category 4)
- Aspiration Hazard (Category 1)
Label Elements:
- Signal Word: Danger
- Hazard Statements:
- H302: Harmful if swallowed.
- H336: May cause drowsiness or dizziness.
- H373: May cause damage to organs through prolonged or repeated exposure.
- H304: May be fatal if swallowed and enters airways.
- Precautionary Statements:
- P260: Do not breathe dust/fume/gas/mist/vapors/spray.
- P264: Wash hands thoroughly after handling.
- P280: Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P310: IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
- P331: Do NOT induce vomiting.
Section 3: Composition/Information on Ingredients
Chemical Name: Toluene
CAS Number: 108-88-3
Concentration: 100%
Section 4: First-Aid Measures
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Skin Contact: Wash off immediately with soap and plenty of water.
Eye Contact: Rinse thoroughly with plenty of water for at least 15 minutes and seek medical attention.
Ingestion: Rinse mouth. Do not induce vomiting. Immediately call a poison center or doctor.
Section 5: Fire-Fighting Measures
Suitable Extinguishing Media: Foam, carbon dioxide, dry powder, water fog.
Specific Hazards: Combustible liquid. May form explosive vapor-air mixture.
Protective Equipment: Wear self-contained breathing apparatus and protective clothing for firefighting.
Section 6: Accidental Release Measures
Personal Precautions: Wear protective equipment. Avoid breathing vapors.
Environmental Precautions: Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods for Cleaning Up: Absorb with inert absorbent material and dispose of according to local regulations.
Section 7: Handling and Storage
Handling: Use only in well-ventilated areas. Avoid breathing vapors. Avoid contact with eyes, skin, and clothing.
Storage: Store in a cool, dry, well-ventilated place. Keep container tightly closed.
Section 8: Exposure Controls/Personal Protection
Exposure Limits:
- OSHA PEL: 200 ppm (TWA), 300 ppm (Ceiling)
- ACGIH TLV: 50 ppm (TWA), 150 ppm (STEL)
Engineering Controls: Provide adequate ventilation.
Personal Protective Equipment:
- Respiratory Protection: Use NIOSH-approved respirator if exposure limits are exceeded.
- Hand Protection: Use chemical-resistant gloves.
- Eye Protection: Use safety goggles or face shield.
- Skin and Body Protection: Use appropriate protective clothing.
Section 9: Physical and Chemical Properties
- Appearance: Clear, colorless liquid
- Odor: Aromatic, sweet
- pH: Not applicable
- Melting Point: -95°C
- Boiling Point: 111°C
- Flash Point: -4°C
- Flammability: Flammable liquid
- Density: 0.866 g/cm³
- Solubility: Insoluble in water, miscible with many organic solvents
Section 10: Stability and Reactivity
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: Heat, flames, sparks, and other ignition sources.
Incompatible Materials: Strong oxidizing agents, acids, bases.
Hazardous Decomposition Products: Carbon oxides, hydrogen cyanide.
Section 11: Toxicological Information
Acute Toxicity:
- Oral LD50: 6360 mg/kg (rat)
- Dermal LD50: >5000 mg/kg (rabbit)
- Inhalation LC50: 25,000 ppm (4-hour exposure, rat)
Skin Corrosion/Irritation: Mild irritant.
Serious Eye Damage/Irritation: Causes severe eye irritation.
Respiratory or Skin Sensitization: Not a sensitizer.
Carcinogenicity: IARC Group 3 – Not classifiable as to its carcinogenicity to humans.
Section 12: Ecological Information
Ecotoxicity: Toxic to aquatic life with long-lasting effects.
Persistence and Degradability: Biodegradable.
Bioaccumulative Potential: Low bioaccumulation potential.
Mobility in Soil: Moderate mobility in soil.
Section 13: Disposal Considerations
Dispose of in accordance with local, regional, national, and international regulations.
Section 14: Transport Information
UN Number: 1294
Proper Shipping Name: Toluene
Transport Hazard Class: 3
Packing Group: II
Section 15: Regulatory Information
Complies with all applicable regulations.
| Weight | 25 kg |
|---|---|
| size | 1Lt, 2,5Lt, 5Lt, 25Lt |
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